Yes, you can certainly eat an orange at 10 pm. There's no specific time when you should or shouldn't eat fruits like oranges. If you feel hungry or want a healthy snack, an orange can be a nutritious choice. Just be mindful of your own tolerance to acidic foods, especially if you have any digestive issues or sensitivities. If eating an orange at 10 pm doesn't cause discomfort for you, then it's perfectly fine.
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